Excess molar enthalpies for the binary and ternary mixtures of ether compounds (di-isopropyl ether, di-butyl ether, propyl vinyl ether) with ethanol and isooctane at 298.15 K

被引:10
|
作者
Kim, Moon-Gab [2 ]
Park, So-Jin [1 ]
Hwang, In-Chan [1 ]
机构
[1] Chungnam Natl Univ, Dept Chem Engn, Taejon 305764, South Korea
[2] Sangju Natl Univ, Sch Appl Chem Engn, Sangju 742711, South Korea
关键词
Excess Molar Enthalpy (H-E); DIPE (di-isopropyl ether); DBE (di-butyl ether); PVE (propyl vinyl ether); Ethanol; Isooctane;
D O I
10.1007/s11814-008-0191-2
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Excess molar enthalpy (H-E) data at 298.15 K are reported for the binary systems di-isopropyl ether (1)+ ethanol (2), di-isopropyl ether (1)+isooctane (2), ethanol (1)+isooctane (2), di-butyl ether (1)+ethanol (2), di-butyl ether (1)+isooctane (2), propyl vinyl ether (1)+ethanol (2) and propyl vinyl ether (1)+isooctane (2). These data were obtained by using an isothermal flow calorimeter. The experimental binary H E data were well correlated with the Redlich-Kister model, and infinitely dilute partial excess molar enthalpies for each binary were calculated with the fitted Redlich-Kister parameters. Additionally, the isoclines of H E for ternary systems di-isopropyl ether (1)+ethanol (2)+isooctane (3), di-butyl ether (1)+ethanol (2)+isooctane (3) and propyl vinyl ether (1)+ethanol (2)+isooctane (3) at 298.15 K were calculated by using the Radojkovic equation. H-E for all the measured systems in this work shows that mixing is endothermic.
引用
收藏
页码:1160 / 1164
页数:5
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