A 3-D pillar-layered coordination polymer {[EuCu(C2O4)(na)2]•2H2O}n:: synthesis, structure and photoluminescent properties

被引：6
|
作者：
He, Yongke [1 ]
Li, Juan [2 ]
Zhang, Peng [1 ]
Chen, Xia [1 ]
Ma, Yi [1 ]
Han, Zhengbo [1 ]
机构：
[1] Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China
[2] Jilin Univ, Sch Publ Hlth, Changchun 130021, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 18期
关键词：
synthesis; structure; coordination polymer; photoluminescent properties;
D O I：
10.1080/00958970801986825
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A 3d-4f heterometallic coordination polymer, {[EuCu(C2O4)(na)2]center dot 2H(2)O}(n) (1) [Hna=nicotinic acid], has been synthesized by hydrothermal reaction of lanthanide oxides, Cu(1). and pyridine-2,3-dicarboxylic acid. I features a 3-D pillar-layered coordination framework constructed from two-dimensional lanthanide-carboxylate layers and Cu(na) pillars. Interestingly, the na ligand was obtained by the in situ decarboxylation of pyridine-2,3-dicarboxylic acid.
引用
收藏
页码：2876 / 2883
页数：8
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