Synthesis, characterisation and thermal properties of [Cu(VO)2(C2O4)3(4,4′-bpy)2•2H2O]A 2d polymer

被引：6

作者：

Vlad, M. ^{[2
]}

Labadi, I. ^{[1
]}

Saity, L. ^{[2
]}

Tudose, R. ^{[2
]}

Linert, W. ^{[3
]}

Costisor, O. ^{[2
]}

机构：

[1] Univ Szeged, Dept Inorgan & Analyt Chem, H-6701 Szeged, Hungary

[2] Timisoara Romanian Acad, Inst Chem, Inorgan Chem Div, Timisoara 300223, Romania

[3] Vienna Univ Technol, Inst Appl Synthet Chem, A-1060 Vienna, Austria

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2008年 / 91卷 / 03期

关键词：

4,4'-bipyridine; copper; IR; oxalate ligand; thermal analysis; vanadium; UV-Vis;

D O I：

10.1007/s10973-006-8275-x

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The heterometallic complex [Cu(VO)(2)(C10H8N2)(2)(C2O4)(3)center dot 2H(2)O] has been prepared and characterised by electronic and IR spectra, molecular electrical conductivity and thermal behaviour. A polymeric structure is proposed with oxalate and 4,4'-dipyridine acting as bridging ligands and VO(IV) Of C-4v symmetry and Cu(II) in octahedral surrounding the oxalate anion V-4h.

引用

页码：925 / 928

页数：4

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