Stoichiometric and Structural Diversity of Silver Hydroxymethylacetylenide Coordination Polymers

被引:3
|
作者
Chupina, Anastasiya, V [1 ,2 ]
Korolkov, Ilya [1 ]
Abramov, Pavel A. [1 ,3 ]
Sokolov, Maxim N. [1 ]
机构
[1] Nikolaev Inst Inorgan Chem SB RAS, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, 2 Pirogova St, Novosibirsk 630090, Russia
[3] South Ural State Univ, 76 Lenina St, Chelyabinsk 454080, Russia
基金
俄罗斯基础研究基金会;
关键词
Silver; Hydroxymethylacetylenide; Coordination polymers; XRD; ACETYLIDE DIANION; ALKYNYL CAGE; CLUSTER; ACETYLENEDIIDE; NANOCLUSTER; COLUMN;
D O I
10.1002/ejic.202000546
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Addition of in situ generated hydroxymethylacetylenide (terminal C-deprotonated propargylic alcohol, prop-2-yn-1-ol, C3H3OH) to aqueous solutions of AgNO(3)in 1:1 molar ratio results in the formation of two new coordination polymers, {AgNO3 center dot 2[Ag(C3H2OH)]center dot(2)/3H2O}(infinity)(1) and {AgNO3 center dot 3Ag(C3H2OH)}(infinity)(2). Storage of crystalline samples of1or2under mother liquor at 5 degrees C for two weeks results in a new crystalline phase, {AgNO3 center dot 2[Ag(C3H2OH)]center dot H2O}(infinity)(3). Another two weeks evolution yields {AgNO3 center dot 2Ag(C3H2OH)}(infinity)(4). This product can be prepared in high scale by changing the reagent ratio between the hydroxymethylacetylenide and AgNO(3)to 0.5:1. All products are colorless crystalline materials, and their structures were determined by single-crystal X-ray diffraction. They are highly light sensitive, in particular, in the presence of trace amounts of impurities.
引用
收藏
页码:3666 / 3672
页数:7
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