The formation, annealing and self-compression of carbon onions under electron irradiation

被引:157
|
作者
Banhart, F
Fuller, T
Redlich, P
Ajayan, PM
机构
[1] Max-Planck-Inst. fur Metallforschung, D-70569 Stuttgart
[2] Rensselear Polytechnic Institute, Troy
关键词
D O I
10.1016/S0009-2614(97)00269-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Electron irradiation-induced basal plane disordering in single- and multi-shell carbon nanotubes and onions is found to be inhibited at irradiation temperatures above 300 degrees C. Irradiation-induced defects anneal out due to the thermally activated migration of interstitials at elevated temperatures and leave behind perfectly coherent shells of high tensile stability. Continuous loss of atoms as a result of sputtering induces a surface tension which can be identified as the origin of the formation and self-compression of spherical concentric-shell carbon onions.
引用
收藏
页码:349 / 355
页数:7
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