Synthesis and structures of a triply-fused incomplete-cubane cluster [{(η5-C5Me5)WS3}3Cu7(MeCN)9](PF6)4 and a 2D polymer [(η5-C5Me5)WS3Cu3Cl(MeCN)(pz)]PF6 (pz = pyrazine)

被引：55

作者：

Lang, JP

Kawaguchi, H

Tatsumi, K

机构：

[1] Nagoya Univ, Grad Sch Sci, Res Ctr Mat Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 22期

关键词：

D O I：

10.1039/a906081b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of PPh4[(eta(5)-C5Me5)WS3] with 3 equiv. of [Cu(MeCN)(4)]PF6 in MeCN yielded an unusual high nuclearity W/Cu/S cluster [{(eta(5)-C5Me5)WS3}(3)Cu-7- (MeCN)(9)](PF6)(4) 1, which in turn gave rise to a 2D polymer [(eta(5)-C5Me5)WS3Cu3Cl(MeCN)(pz)]PF6 2 upon treatment with pyrazine in MeCN in the presence of LiCl.

引用

页码：2315 / 2316

页数：2

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