Synthesis and structures of a triply-fused incomplete-cubane cluster [{(η5-C5Me5)WS3}3Cu7(MeCN)9](PF6)4 and a 2D polymer [(η5-C5Me5)WS3Cu3Cl(MeCN)(pz)]PF6 (pz = pyrazine)

被引：55
|
作者：
Lang, JP
Kawaguchi, H
Tatsumi, K
机构：
[1] Nagoya Univ, Grad Sch Sci, Res Ctr Mat Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan
来源：
CHEMICAL COMMUNICATIONS | 1999年 / 22期
关键词：
D O I：
10.1039/a906081b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of PPh4[(eta(5)-C5Me5)WS3] with 3 equiv. of [Cu(MeCN)(4)]PF6 in MeCN yielded an unusual high nuclearity W/Cu/S cluster [{(eta(5)-C5Me5)WS3}(3)Cu-7- (MeCN)(9)](PF6)(4) 1, which in turn gave rise to a 2D polymer [(eta(5)-C5Me5)WS3Cu3Cl(MeCN)(pz)]PF6 2 upon treatment with pyrazine in MeCN in the presence of LiCl.
引用
收藏
页码：2315 / 2316
页数：2
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