First example of [6π+2π] cycloaddition of 1,2-dienes to 1,3,5,7-cyclooctatetraene catalyzed by CoI compounds

被引：4
|
作者：
D'Yakonov, V. A. [1 ]
Kadikova, G. N. [1 ]
Gazizullina, G. F. [1 ]
Dzhemilev, U. M. [1 ]
机构：
[1] Russian Acad Sci, Inst Petrochem & Catalysis, 141 Prosp Oktyabrya, Ufa 450075, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2016年 / 65卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
homogeneous metal complex catalysis; cycloaddition; 1,3,5,7-cyclooctatetraene; 1,2-dienes; cobalt(II) iodide; bicyclo[4.2.2]deca-2,4,7-trienes; ALKYNES; CYCLOHEPTATRIENE;
D O I：
10.1007/s11172-016-1284-4
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A stereoselective [6 pi+2 pi] cycloaddition of 1,2-dienes to 1,3,5,7-cyclooctatetraene in the presence of a multi-component catalytic system CoI2/dppe/Zn/ZnI2, which led to the formation of substituted (E)-bicyclo[4.2.2]deca-2,4,7-trienes in 76-87% yields, was accomplished for the first time.
引用
收藏
页码：200 / 202
页数：3
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