One neutral metal-organic framework with an unusual dmp topology for adsorption of dyes

被引：18
|
作者：
Qin, Ling [1 ,2 ,3 ]
Zeng, Si-Ying [1 ]
Zuo, Wei-Juan [1 ]
Liu, Qing-He [1 ]
Li, Jin [1 ]
Ni, Gang [1 ]
Wang, Yan-Qing [1 ]
Zhang, Ming-Dao [2 ]
机构：
[1] Hefei Univ Technol, Dept Chem Engn & Food Proc, Xuancheng Campus, Xuancheng 242000, Anhui, Peoples R China
[2] Nanjing Univ Informat Sci & Technol, Jiangsu Engn Technol Res Ctr Environm Cleaning Ma, Sch Environm Sci & Engn, Nanjing 210044, Jiangsu, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing Natl Lab Microstruct, Nanjing 210093, Jiangsu, Peoples R China
来源：
POLYHEDRON | 2017年 / 121卷
关键词：
Coordination polymer; mixed ligands; dmp topology; 3-Fold interpenetration; Dye uptake; SELECTIVE ADSORPTION; PORE STRUCTURE; WASTE-WATER; REMOVAL; CARBON; MOFS; CONSTRUCTION; MOLECULES; THIOETHER; LIGANDS;
D O I：
10.1016/j.poly.2016.09.063
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
One new Co-based coordination polymer with a bidentate imidazole ligand, 4,4'-bisimidazolylbiphenyl (4,4'-bibp), and a 1,4-benzenedicarboxylate (1,4-bdc) co-ligand, [Co(bibp)(bdc)](n) (1) has been synthesized under hydrothermal conditions. For complex 1, the mixed ligands linked the Co(II) ions to form a three dimensional 4-connected net with a rare dmp topology, in which a large cavity causes 3-fold inter-penetration of the network. Dye adsorption studies confirmed that 1 can selectively adsorb the organic dyes methyl orange, methyl blue, neutral red, Sudan I and methylene blue, but hardly adsorb Safranine T. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：231 / 235
页数：5
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