A new metal-organic framework with suitable pore size and ttd-type topology revealing highly selective adsorption and separation of organic dyes

被引:22
|
作者
Duan, Xing [1 ,2 ]
Lv, Ran [1 ]
Shi, Zhenzong [1 ]
Wang, Chao [1 ]
Li, Hecheng [1 ]
Ge, Jingyuan [1 ]
Ji, Zhenguo [1 ]
Yang, Yu [3 ]
Li, Bin [3 ]
Qian, Guodong [3 ]
机构
[1] Hangzhou Dianzi Univ, Coll Mat & Environm Engn, Hangzhou 310027, Zhejiang, Peoples R China
[2] Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
[3] Zhejiang Univ, Sch Mat Sci & Engn, Cyrus Tang Ctr Sensor Mat & Applicat, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Metal-organic frameworks; Crystal structure; Crystal growth; Dye adsorption and separation; WATER; PHARMACEUTICALS; REMOVAL; CHEMICALS; CO2;
D O I
10.1016/j.jssc.2019.06.012
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A microporous metal-organic framework (MOF) with ttd-type topology, [Mn-2(FDDI)](DMF)(5.5)(H2O)(4.5) (Mn-MOF; H4FDDI = 5,5'-(9H-fluorene-2,7-diyl)-diisophthalic acid (DMF = C3H7NO) was solvothermal obtained and characterized. Mn-MOF contains three different channels that show excellent removal of low concentration of crystal violet as compared with methyl orange and methylene blue from the aqueous solution at 298 K.
引用
收藏
页码:159 / 162
页数:4
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