Thermal and spectroscopic studies on solid Ketoprofen of lighter trivalent lanthanides

被引：25
|
作者：
Galico, D. A. [1 ]
Holanda, B. B. [1 ]
Perpetuo, G. L. [1 ]
Schnitzler, E. [2 ]
Treu-Filho, O. [3 ]
Bannach, G. [1 ]
机构：
[1] UNESP, Fac Ciencias, Dept Quim, BR-17033260 Bauru, SP, Brazil
[2] Univ Estadual Ponta Grossa, Dept Quim, BR-84030900 Ponta Grossa, PR, Brazil
[3] UNESP, Inst Quim, BR-14800900 Araraquara, SP, Brazil
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2012年 / 108卷 / 01期
基金：
巴西圣保罗研究基金会;
关键词：
Ketoprofen; Thermal behavior; Infrared spectroscopy; Carboxylate coordination; COMPOUND;
D O I：
10.1007/s10973-011-1866-1
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Solid-state Ln(L)(3) compounds, where Ln stands for trivalent La, Ce, Pr, Nd, Sm, Eu, and L is ketoprofen have been synthesized. Thermogravimetry (TG), differential thermal analysis (DTA), differential scanning calorimetry (DSC) as well as X-ray diffraction powder (DRX) patterns, Fourier transformed infrared spectroscopy (FTIR), and other methods of analysis were used to study solid Ketoprofen of lighter trivalent lanthanides. The results provided information of the composition, dehydration, coordination mode, structure, thermal behavior, and thermal decomposition. The theoretical and experimental spectroscopic study suggests that the carboxylate group of ketoprofen is coordinate to metals as bidentate bond.
引用
收藏
页码：371 / 379
页数：9
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