Silica-supported PEI capped nanopalladium as potential catalyst in Suzuki, Heck and Sonogashira coupling reactions

被引：62
|
作者：
Veerakumar, Pitchaimani [1 ,3 ]
Velayudham, Murugesan [2 ]
Lu, Kuang-Lieh [2 ]
Rajagopal, Seenivasan [1 ]
机构：
[1] Madurai Kamaraj Univ, Sch Chem, Dept Phys Chem, Madurai 625021, Tamil Nadu, India
[2] Acad Sinica, Inst Chem, Taipei 115, Taiwan
[3] Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan
来源：
APPLIED CATALYSIS A-GENERAL | 2013年 / 455卷
关键词：
Silica; Heterogeneous; Palladium; Polyethylenimine; Catalysis; EFFICIENT HETEROGENEOUS CATALYST; PHOSPHINE-FREE CATALYST; PALLADIUM NANOPARTICLES; PD NANOPARTICLES; CARBON-CARBON; SILVER NANOPARTICLES; LIGAND-FREE; METAL NANOPARTICLES; MESOPOROUS SILICA; IONIC LIQUIDS;
D O I：
10.1016/j.apcata.2013.01.021
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We present the use of amine-functionalized silica (NH2-SiO2) as support for palladium nanoparticles (PdNPs) and the use of heterogeneous catalysts (Pd/NH2-SiO2) for the Suzuki, Heck and Sonogashira coupling reactions. The synthesized Pd catalyst is well characterized by XRD, HRTEM, BET, SEM-EDX, FT-IR, and UV-vis spectral techniques. It exhibits efficient catalytic activity for these coupling reactions without the assistance of ligand and copper salts. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：247 / 260
页数：14
相关论文
共 50 条
  • [21] Silica-supported 3-4,5-dihydroimidazol-1-yl-propyltriethoxysilanedichloropalladium(II) complex:: Heck and Suzuki cross-coupling reactions
    Gurbuz, N
    Özdemir, I
    Çetinkaya, B
    Seçkin, T
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2003, 17 (10) : 776 - 780
  • [22] Transition metal nanoparticles as nanocatalysts for Suzuki, Heck and Sonogashira cross-coupling reactions
    Ashraf, Muhammad
    Ahmad, Muhammad Sohail
    Inomata, Yusuke
    Ullah, Nisar
    Tahir, Muhammad Nawaz
    Kida, Tetsuya
    [J]. COORDINATION CHEMISTRY REVIEWS, 2023, 476
  • [23] Mesoporous silica SBA-15-supported palladium catalyst for green Sonogashira coupling reactions
    Jin, Myung-Jong
    Sarkar, M. S.
    Lee, Dong-Hwan
    Lee, Ik-Mo
    [J]. RECENT PROGRESS IN MESOSTRUCTURED MATERIALS, PROCEEDINGS OF THE 5TH INTERNATIONAL MESOSTRUCTURED MATERIALS SYMPOSIUM - IMMS2006, 2007, 165 : 709 - 712
  • [24] Palladium ethylthioglycolate modified silica - a new heterogeneous catalyst for Suzuki and Heck cross-coupling reactions
    Al-Hashimi, Mohammed
    Sullivan, Alice C.
    Wilson, John R. H.
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 273 (1-2) : 298 - 302
  • [25] Highly efficient silica gel-supported 1,2-diaminocyclohexane-Pd catalyst for Suzuki-Miyaura and Sonogashira coupling reactions
    Sarkar, Shaheen M.
    Alam, Md. Nazmul
    Miah, Md. Rezwan
    [J]. REACTION KINETICS AND CATALYSIS LETTERS, 2009, 96 (01): : 175 - 183
  • [26] Highly efficient silica gel-supported 1,2-diaminocyclohexane-Pd catalyst for Suzuki-Miyaura and Sonogashira coupling reactions
    Shaheen M. Sarkar
    Md. Nazmul Alam
    Md. Rezwan Miah
    [J]. Reaction Kinetics and Catalysis Letters, 2009, 96 : 175 - 183
  • [27] Palladium Supported on a Polyionic Resin as an Efficient, Ligand-Free, and Recyclable Catalyst for Heck, Suzuki-Miyaura, and Sonogashira Reactions
    Basu, Basudeb
    Das, Sajal
    Das, Pralay
    Mandal, Bablee
    Banerjee, Dipanjan
    Almqvist, Fredrik
    [J]. SYNTHESIS-STUTTGART, 2009, (07): : 1137 - 1146
  • [28] Palladium Nanoparticles Supported on a Porous Organic Polymer: An Efficient Catalyst for Suzuki-Miyaura and Sonogashira Coupling Reactions
    Ren, Xiaomeng
    Kong, Shengnan
    Shu, Qiding
    Shu, Mouhai
    [J]. CHINESE JOURNAL OF CHEMISTRY, 2016, 34 (04) : 373 - 380
  • [29] Preparation of a novel silica-supported palladium catalyst and its use in the Heck reaction
    Clark, JH
    Macquarrie, DJ
    Mubofu, EB
    [J]. GREEN CHEMISTRY, 2000, 2 (02) : 53 - 55
  • [30] Computational Studies of Versatile Heterogeneous Palladium-Catalyzed Suzuki, Heck, and Sonogashira Coupling Reactions
    Veerakumar, Pitchaimani
    Thanasekaran, Pounraj
    Lu, Kuang-Lieh
    Lin, King-Chuen
    Rajagopal, Seenivasan
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (10): : 8475 - 8490
12345