(Z)-2,3-bis(4'-[2.2.2]paracyclophanyl)but-2-ene and mu-eta(6):eta(6)-[(Z)-2,3-bis(4'-[2.2.2]-paracyclophanyl)but-2-ene]-bis[(hexafluoroantimonato-F)silver(I)] toluene dichloromethane (1/1/1)

被引：26

作者：

Jones, PG ^{[1
]}

Bubenitschek, P ^{[1
]}

Heirtzler, F ^{[1
]}

Hopf, H ^{[1
]}

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ORGAN CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195017008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The free Ligand, C52H52, displays approximate twofold symmetry, with a C=C bond of 1.337 (4) Angstrom and essentially planar olefin geometry. The (methyl C)-(olefin C)-(cyclophane C) angles are narrow [113.0 (2)degrees]. In the disilver(I) complex, [Ag-2(SbF6)(2)(C52H52)].C7H8.CH2Cl2, the olefin geometry is not greatly changed, The Ag-C distances vary from 2.498 to 2.696 (5) Angstrom and there is a short Ag-F contact of 2.545 (4) Angstrom. The dichloromethane molecule occupies the cleft between the primary aromatic rings.

引用

页码：1380 / 1384

页数：5

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