NMR Studies on 1,3-Dipolar Cycloaddition of Nitrile Oxides to Norbornenes

被引：11
|
作者：
Gucma, Miroslaw [1 ]
Golebiewski, W. Marek [1 ]
Krawczyk, Maria [1 ]
机构：
[1] Inst Ind Organ Chem, PL-03236 Warsaw, Poland
来源：
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY | 2013年 / 24卷 / 05期
关键词：
1,3-dipolar cycloaddition; norbornenes; nitrile oxides; 2D NMR; ADDITIONS;
D O I：
10.5935/0103-5053.20130106
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The 1,3-dipolar cycloaddition reaction of nitrile oxides to norbornenes substituted with an acrylate-derived moiety was examined. Only adducts to norbornene system were formed with a good exo selectivity and complete site-selectivity. Structures of the products were elucidated by an extensive application of electrospray ionization-mass spectrometry (ESI-MS) and 2D H-1 and C-13 nuclear magnetic resonance (NMR).
引用
收藏
页码：805 / +
页数：25
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