NMR Studies on 1,3-Dipolar Cycloaddition of Nitrile Oxides to Norbornenes

被引：11

作者：

Gucma, Miroslaw ^{[1
]}

Golebiewski, W. Marek ^{[1
]}

Krawczyk, Maria ^{[1
]}

机构：

[1] Inst Ind Organ Chem, PL-03236 Warsaw, Poland

来源：

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY | 2013年 / 24卷 / 05期

关键词：

1,3-dipolar cycloaddition; norbornenes; nitrile oxides; 2D NMR; ADDITIONS;

D O I：

10.5935/0103-5053.20130106

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 1,3-dipolar cycloaddition reaction of nitrile oxides to norbornenes substituted with an acrylate-derived moiety was examined. Only adducts to norbornene system were formed with a good exo selectivity and complete site-selectivity. Structures of the products were elucidated by an extensive application of electrospray ionization-mass spectrometry (ESI-MS) and 2D H-1 and C-13 nuclear magnetic resonance (NMR).

引用

页码：805 / +

页数：25

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