Synthesis of vanadium(V) hydrazido complexes with tris(2-hydroxyphenyl)amine ligands

被引：7
|
作者：
Moriuchi, Toshiyuki [1 ]
Ikeuchi, Kousuke [1 ]
Hirao, Toshikazu [1 ,2 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[2] JST, ACT C, Kawaguchi, Saitama 3320012, Japan
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 33期
关键词：
NITROGEN-FIXATION; COORDINATION CHEMISTRY; CO-LIGANDS; DINITROGEN; RELEVANT; (ARYLIMIDO)VANADIUM(V); ASSOCIATION; CRYSTAL;
D O I：
10.1039/c3dt50533b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the oxidovanadium(V) complexes with N,N-dimethylhydrazine was demonstrated to afford the corresponding vanadium(V) dimethylhydrazido complexes. The substituent at the 3-position of the tris(2-hydroxyphenyl)amine ligand was found to influence the electronic environment of the vanadium center. The crystal structure of the non-substituted vanadium(V) dimethylhydrazido complex exhibited a distorted trigonal bipyramidal geometry with phenolate oxygen atoms in equatorial positions and the near-linear V(1)-N(2)-N(3) angle. The vanadium(V) diphenylhydrazido complexes could be obtained by the reaction of the oxidovanadium(V) complexes with N,N-diphenylhydrazine. A distorted trigonal bipyramidal geometry with phenolate oxygen atoms in equatorial positions was also observed in the crystal structure of the non-substituted vanadium(V) diphenylhydrazido complex.
引用
收藏
页码：11824 / 11830
页数：7
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