Anion binding properties of tris(2-hydroxyphenyl)methanes

被引：6
|
作者：
Sato, Tatsunori [1 ]
Ito, Kazuaki [1 ]
机构：
[1] Yamagata Univ, Grad Sch Sci & Engn, Dept Chem & Chem Engn, Yonezawa, Yamagata 9928510, Japan
来源：
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2013年 / 77卷 / 1-4期
关键词：
Tris(2-hydroxyphenyl)methane; Anion receptor; Hydroxyl group; QUATERNARY AMMONIUM-SALTS; HOST-GUEST COMPLEXATION; MOLECULAR RECOGNITION; HYDROGEN-BOND; DERIVATIVES; RECEPTORS; HIGHLIGHTS; CATECHOL; HALIDES; IONS;
D O I：
10.1007/s10847-012-0258-x
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Tris(2-hydroxyphenyl)methane derivatives (1) displayed excellent selectivity for Cl- in comparison with other anions tested (Br-, I- and NO3 (-)) by H-1 NMR titration experiments. This selectivity is attributed to the fit size and shape of Cl-, which favor the formation of a stable host-guest complex with 1 through the multiple intermolecular hydrogen bonds.
引用
收藏
页码：385 / 394
页数：10
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