Post-Functionalization of a ROMP Polymer Backbone Via Radical Thiol-ene Coupling Chemistry

被引：39

作者：

van Hensbergen, Johannes Arend ^{[1
]}

Burford, Robert P. ^{[1
]}

Lowe, Andrew B. ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem Engn, CAMD, Sydney, NSW 2052, Australia

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2013年 / 51卷 / 03期

基金：

澳大利亚研究理事会;

关键词：

backbone; functional polymer; heteroatom-containing polymers; hydrothiolation; radical thiol-ene; ROMP; synthesis; OPENING METATHESIS POLYMERIZATION; OLEFIN METATHESIS; POLYNORBORNENES; REACTIVITY; CATALYSTS;

D O I：

10.1002/pola.26433

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The radical thiol-ene reaction is used to modify the backbone of a common ROMP-prepared homopolymer. Hydrothiolation is successful in most instances in facilitating the ready introduction of a range of functionality including OH, pyrrole, alkyl, ester, and POSS species while still retaining the well-defined characteristics of the parent polymer. Copyright © 2012 Wiley Periodicals, Inc.

引用

页码：487 / 492

页数：6

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