Post-Functionalization of a ROMP Polymer Backbone Via Radical Thiol-ene Coupling Chemistry

被引：39
|
作者：
van Hensbergen, Johannes Arend [1 ]
Burford, Robert P. [1 ]
Lowe, Andrew B. [1 ]
机构：
[1] Univ New S Wales, Sch Chem Engn, CAMD, Sydney, NSW 2052, Australia
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2013年 / 51卷 / 03期
基金：
澳大利亚研究理事会;
关键词：
backbone; functional polymer; heteroatom-containing polymers; hydrothiolation; radical thiol-ene; ROMP; synthesis; OPENING METATHESIS POLYMERIZATION; OLEFIN METATHESIS; POLYNORBORNENES; REACTIVITY; CATALYSTS;
D O I：
10.1002/pola.26433
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The radical thiol-ene reaction is used to modify the backbone of a common ROMP-prepared homopolymer. Hydrothiolation is successful in most instances in facilitating the ready introduction of a range of functionality including OH, pyrrole, alkyl, ester, and POSS species while still retaining the well-defined characteristics of the parent polymer. Copyright © 2012 Wiley Periodicals, Inc.
引用
收藏
页码：487 / 492
页数：6
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