Generation of 6H-benzo[f] cyclopenta[d][1,2] thiazepine 5,5-dioxides via a palladium-catalyzed reaction of 2-(2-alkynyl) benzenesulfonamide

被引：8

作者：

Wang, Huanhuan ^{[1
]}

Luo, Yong ^{[1
]}

Hou, Xiufeng ^{[1
]}

Wu, Jie ^{[1
,2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 13期

基金：

中国国家自然科学基金;

关键词：

DIVERSITY-ORIENTED SYNTHESIS; ORGANIC-SYNTHESIS; 3-COMPONENT REACTION; DESIGN; 2-ALKYNYLANILINE; CYCLIZATIONS; CHEMISTRY; DISCOVERY; ACTIVATOR; SWITCHES;

D O I：

10.1039/c2dt32452k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An efficient approach for the assembly of 6H-benzo[f] cyclopenta[d][ 1,2] thiazepine 5,5-dioxides via a palladium-catalyzed tandem reaction of 2-(2-alkynyl) benzenesulfonamide with 2-alkynylvinyl bromide is reported. This transformation proceeds smoothly through a double carbopalladation with high efficiency.

引用

页码：4410 / 4415

页数：6

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