Study of the synthesis and properties of the ternary complexes of rare earths with mandelic acid and 1,10-phenanthroline

被引：4

作者：

Ren, YP ^{[1
]}

Yan, GL ^{[1
]}

Zhang, L ^{[1
]}

Yu, KY ^{[1
]}

Wang, LF ^{[1
]}

Wu, JG ^{[1
]}

机构：

[1] LANZHOU UNIV,DEPT CHEM,LANZHOU 730000,PEOPLES R CHINA

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1996年 / 26卷 / 02期

关键词：

D O I：

10.1080/00945719608004265

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fourteen ternary complexes of rare earths with mandelic acid (MAH) and 1,10-phenanthroline (phen) have been prepared in aqueous solution. The composition of the ternary complexes has been determined as RE(MA)(3) . phen . nH(2)O (RE = La, Ce, Pr, Nd, n = 0; RE = Sm, n 1/2; RE Eu, Gd, Dy-Lu, Y, n = 1) by elemental and chemical analyses, Their solubility in different solvents and molar conductances were measured. The structures and properties of the ternary complexes were investigated using IR, TGA, X-ray powder diffraction and UV. The bonding character of the complexes are also discussed.

引用

页码：293 / 303

页数：11

共 50 条

[31] Synthesis and Luminescence Study of Europium Complexes with Carboxylic Acid and 1,10-Phenanthroline Ligands
QIAN Dong-jin and ZHANG Shu-zhen (Department of Chemistry
Chemical Research in Chinese Universities, 1993, (03) : 181 - 187
[32] Study on the synthesis and properties of complexes of rare earth trichloroacetic acid with two 1, 10-phenanthroline
Wang, Jun-Rui
Journal of Rare Earths, 1992, 10 (01)
[33] Synthesis, structures and properties of Cu and Cd complexes with 1,10-phenanthroline
Sun, Jingya
Tong, Xiangdi
Xu, Huanzhi
INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (05) : 645 - 648
[34] Synthesis, luminescence, energy transfer of binary and ternary rare-earth complexes with 5-sulfosalicylic acid and 1,10-phenanthroline
Yan, B
Zhang, H
Wang, S
Ni, J
CHEMICAL PAPERS-CHEMICKE ZVESTI, 1998, 52 (04): : 199 - 204
[35] Photophysical Properties of Rare Earth Complexes with 3,4-Furandicarboxylic Acid and 1,10-Phenanthroline
闫冰
张洪杰
王淑彬
倪嘉缵
Journal of Rare Earths, 1999, (01) : 17 - 20
[36] Photophysical properties of rare earth complexes with 3,4-furandicarboxylic acid and 1,10-phenanthroline
Yan, B
Zhang, HJ
Wang, SB
Ni, JZ
JOURNAL OF RARE EARTHS, 1999, 17 (01) : 16 - 19
[37] RARE-EARTH BROMIDE COMPLEXES WITH 1,10-PHENANTHROLINE
LOBANOV, NI
ZHURNAL NEORGANICHESKOI KHIMII, 1972, 17 (10): : 2844 - &
[38] PHOTOMETRIC DETERMINATION OF CERTAIN RARE EARTHS BY MEANS OF 1,10-PHENANTHROLINE AND TETRABROMOFLUORESCEIN
POLUEKTOV, NS
SANDU, MA
ZHURNAL ANALITICHESKOI KHIMII, 1970, 25 (08): : 1510 - +
[39] Studies on luminescence properties of seven ternary complexes of terbium with 1,10-phenanthroline and benzoic acid and its derivatives
Gao, ZH
Wang, SP
Liu, CG
Ma, RX
Wang, RF
SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26 (04) : 678 - 681
[40] Synthesis, characterization, and photophysical properties of rare earth complexes of N-phenyl-2-aminobenzoic acid and 1,10-phenanthroline
Yan, B
Zhang, HJ
Wang, SB
Ni, JZ
MONATSHEFTE FUR CHEMIE, 1998, 129 (6-7): : 567 - 575

← 1 2 3 4 5 →