Efficient, recyclable and phosphine-free carbonylative Suzuki coupling reaction using immobilized palladium ion-containing ionic liquid: synthesis of aryl ketones and heteroaryl ketones

被引：42

作者：

Khedkar, Mayur V. ^{[1
]}

Sasaki, Takehiko ^{[2
]}

Bhanage, Bhalchandra M. ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Chem, Bombay 400019, Maharashtra, India

[2] Univ Tokyo, Dept Complex Sci & Engn, Grad Sch Frontier Sci, Kashiwa, Chiba 2778561, Japan

来源：

RSC ADVANCES | 2013年 / 3卷 / 21期

关键词：

HETEROCYCLIC CARBENE COMPLEX; FRIEDEL-CRAFTS ACYLATION; ORGANOBORON COMPOUNDS; ARYLBORONIC ACIDS; ORGANIC HALIDES; METAL-COMPLEXES; CATALYST; CHLORIDES; IODIDES; AMINOCARBONYLATION;

D O I：

10.1039/c3ra40730f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The carbonylative Suzuki coupling reaction of aryl and heteroaryl iodides was studied by using immobilized palladium ion-containing ionic liquid (ImmPd-IL). The protocol was optimized with respect to various reaction parameters, applied to a wide variety of substituted aryl/heteroaryl iodides and various aryl/heteroaryl boronic acids with different steric and electronic properties, and afforded the corresponding products in good to excellent yield. This is an efficient, heterogeneous catalyst which avoids the use of phosphine ligands, and its reusability was tested in up to four consecutive cycles. The recycled catalyst was characterized by using XPS analysis.

引用

页码：7791 / 7797

页数：7

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