The permanent electric dipole moment and hyperfine interactions in platinum monofluoride, PtF

被引：10

作者：

Qin, Chengbing ^{[1
]}

Zhang, Ruohan ^{[1
]}

Wang, Fang ^{[1
]}

Steimle, Timothy C. ^{[1
]}

机构：

[1] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 2012年 / 137卷 / 05期

关键词：

H BOND ACTIVATION; C-F; ELECTROPHILIC FLUORINATION; AB-INITIO; SPECTROSCOPY; COMPLEXES; CONSTANTS; MECHANISM; SPECTRUM; METHANOL;

D O I：

10.1063/1.4734596

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The [11.9]Omega = 3/2 <- X (2)Pi(3/2)(0,0) and (1,0) bands of platinum monofluoride, PtF, have been recorded field-free and in the presence of a static electric field. The F-19(I = 1/2) and Pt-195(I = 1/2) magnetic hyperfine interactions have been analyzed and compared with predicted values obtained using atomic information and a proposed molecular orbital correlation diagram. The optical Stark shifts were analyzed to produce the permanent electric dipole moments, (mu) over right arrow (el), of 2.47(11)D and 3.42(6)D for the [11.9]Omega = 3/2 and X-2 Pi(3/2) states, respectively. The observed trend in (mu) over right arrow (el) for the PtX (X = C,N,O,S and F) series is discussed and a comparison with IrF made. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4734596]

引用

页数：9

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