Improvement on the phase stability, mechanical properties and thermal insulation of Y2O3-stabilized ZrO2 by Gd2O3 and Yb2O3 co-doping

被引:83
|
作者
Guo, Lei [1 ,2 ]
Guo, Hongbo [1 ,2 ]
Gong, Shengkai [1 ,2 ]
Xu, Huibin [1 ,2 ]
机构
[1] Beihang Univ, Sch Mat Sci & Engn, Beijing 100191, Peoples R China
[2] Beihang Univ, Beijing Key Lab Adv Funct Mat & Thin Film Technol, Beijing 100191, Peoples R China
关键词
Mechanical properties; Thermal conductivity; ZrO2; Thermal applications; BARRIER-COATING APPLICATIONS; THERMOPHYSICAL PROPERTIES; PHYSICAL PROPERTIES; DOPED ZIRCONIA; CONDUCTIVITY; CERAMICS; TRANSFORMATION; YTTRIA; OXIDES; SYSTEMS;
D O I
10.1016/j.ceramint.2013.04.103
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Gd2O3 and Yb2O3 co-doped 3.5 mol% Y2O3-ZrO2 and conventional 3.5 mol% Y2O3-ZrO2 (YSZ) powders were synthesized by solid state reaction. The objective of this study was to improve the phase stability, mechanical properties and thermal insulation of YSZ. After heat treatment at 1500 degrees C for 10 h, 1 mol% Gd2O3-1 mol% Yb2O3 co-doped YSZ (1Gd1Yb-YSZ) had higher resistance to destabilization of metastable tetragonal phase than YSZ. The hardness of 5 mol% Gd2O3-1 mol% Yb2O3 co-doped YSZ (5Gd1Yb-YSZ) was higher than that of YSZ. Compared with YSZ, 1Gd1Yb-YSZ and 5Gd1Yb-YSZ exhibited lower thermal conductivity and shorter phonon mean free path. At 1300 degrees C, the thermal conductivity of 5Gd1Yb-YSZ was 1.23 W/m K, nearly 25% lower than that of YSZ (1.62 W/m K). Gd2O3 and Yb2O3 co-doped YSZ can be explored as a candidate material for thermal bather coating applications. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:9009 / 9015
页数:7
相关论文
共 50 条
  • [21] DETERMINATION OF DENSITY OF TRAP STATES AT Y2O3-STABILIZED ZRO2/SI INTERFACE OF YBA2CU3O7-DELTA/Y2O3-STABILIZED ZRO2/SI CAPACITORS
    QIAO, JM
    WANG, KS
    YANG, CY
    APPLIED PHYSICS LETTERS, 1994, 64 (13) : 1732 - 1734
  • [22] Specific Features of the Local Structure and Transport Properties of ZrO2–Sc2O3–Y2O3 and ZrO2–Sc2O3–Yb2O3 Crystals
    M. A. Borik
    T. V. Volkova
    I. E. Kuritzyna
    N. A. Larina
    E. E. Lomonova
    V. A. Myzina
    P. A. Ryabochkina
    N. Yu. Tabachkova
    Optics and Spectroscopy, 2018, 125 : 898 - 902
  • [23] ELECTRICAL-CONDUCTIVITY OF CR2O3-DOPED Y2O3-STABILIZED ZRO2
    JAYARATNA, M
    YOSHIMURA, M
    SOMIYA, S
    JOURNAL OF MATERIALS SCIENCE, 1987, 22 (06) : 2011 - 2016
  • [24] COMPRESSIVE DEFORMATION OF Y2O3-STABILIZED ZrO2/Al2O3 COMPOSITE.
    Wakai, Fumihiro
    Kato, Hidezumi
    Sakaguchi, Shuji
    Murayama, Norimitsu
    Yogyo Kyokai Shi/Journal of the Ceramic Society of Japan, 1986, 94 (09): : 1017 - 1020
  • [25] HOT-PRESSING OF Y2O3-STABILIZED ZRO2 WITH CR2O3 ADDITIONS
    JAYARATNA, M
    YOSHIMURA, M
    SOMIYA, S
    JOURNAL OF MATERIALS SCIENCE, 1986, 21 (02) : 591 - 596
  • [26] Influence of partial substitution of Sc2O3 with Gd2O3 on the phase stability and thermal conductivity of Sc2O3-doped ZrO2
    Sun, Leilei
    Guo, Hongbo
    Peng, Hui
    Gong, Shengkai
    Xu, Huibin
    CERAMICS INTERNATIONAL, 2013, 39 (03) : 3447 - 3451
  • [27] Effect of the Phase Composition and Local Crystal Structure on the Transport Properties of the ZrO2–Y2O3 and ZrO2–Gd2O3 Solid Solutions
    Agarkova E.A.
    Borik M.A.
    Bublik V.T.
    Volkova T.V.
    Kulebyakin A.V.
    Kuritsyna I.E.
    Larina N.A.
    Lomonova E.E.
    Milovich F.O.
    Myzina V.A.
    Ryabochkina P.A.
    Tabachkova N.Y.
    Russian Microelectronics, 2019, 48 (08): : 523 - 530
  • [28] Mechanical properties of Y2O3-stabilized ZrO2 polycrystals fabricated by the solid phase mixing and sintering method
    Ohnishi, Hiroshi
    Naka, Hironori
    Sekino, Tohru
    Ikuhara, Yuichi
    Niihara, Koichi
    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2008, 116 (1351) : 491 - 496
  • [29] MORPHOLOGY OF TETRAGONAL PRECIPITATES IN Y2O3-STABILIZED ZRO2 CRYSTALS
    BAITHER, D
    BAUFELD, B
    MESSERSCHMIDT, U
    PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1993, 137 (02): : 569 - 576
  • [30] HIGH-TEMPERATURE CREEP OF Y2O3-STABILIZED ZRO2
    SELTZER, MS
    TALTY, PK
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1975, 58 (3-4) : 124 - 130