Amino derivatives of α-P4S3, α-P4Se3, and P3Se4;: data and analyses of their 31P NMR spectra in solution

被引：0

作者：

Lutz, J ^{[1
]}

Nowottnick, H ^{[1
]}

Blachnik, R ^{[1
]}

机构：

[1] Univ Osnabruck, Inst Chem, D-49069 Osnabruck, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 06期

关键词：

P-31; NMR; phosphorus chalcogenides; 2,5-diamino-1,2,4,5-tetraphospha-3,6,7-trichalcogena-bicyclo[2.2.1]heptan; 2-amino-1,2,4-triphospha-3,5,6,7-tetraselena-; bicyclo [2.2.1]heptan; 8-alkyl-8-aza-1,2,3,5-tetraphospha-3,6,7-trithia-tricyclo[2.2.1.1(2,5)]octan;

D O I：

10.1002/(SICI)1521-3749(199906)625:6<1019::AID-ZAAC1019>3.0.CO;2-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

alpha-P4S3I2, alpha-P4Se3I2, and P3Se4I were reacted with primary and secondary amines in CS2. The reaction yields exo-exo isomeres of alpha-P3S3L2 and alpha-P4Se3L2, the N-bridged compounds alpha-P4S3L' and P3Se4L, with L = NHR1, NPhR2 THC (R-1 = 'Bu, Ad, Ph, Flu, TPMP; R-2 = Me, Et, Pr-i), and L'=NR1. The P-31 NMR data of the compounds in CS2 solution were measured. By the reaction of alpha-P4Se3I2 With primary amines NH2'Bu and NH(2)Ad in CS2 an asymmetric isomer alpha-P(4)Se(3)Iendo(NHR1)exo was observed for the first time in the 31P NMR spectra. The influence of the ligands L on the P-31 NMR parameter of alpha-P4S3L2, alpha-P3Se3L2, and P3Se4L is discussed.

引用

页码：1019 / 1024

页数：6

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