Two New Metal-Organic Frameworks Based on 5-Bromoisophthalic Acid and 1,3-bi(4-pyridyl)propane: Hydrothermal Syntheses, Structures, and Magnetic Properties

被引：2
|
作者：
Han, Min-Le [1 ]
Wu, Hai-Xia [1 ]
Zhao, Ke-Yan [1 ]
Zhang, Zu-Qiang [1 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 04期
关键词：
1,3-bi(4-pyridyl)propane; 5-bromoisophthalic acid; crystal structure; magnetic properties; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; LIGAND; POLYROTAXANE; 1,4-BIS(IMIDAZOL-1-YLMETHYL)BENZENE; ASSEMBLIES; NETWORKS; CLUSTERS; SORPTION; ZN(II);
D O I：
10.1080/15533174.2011.613890
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new complexes, [M((H2O)(bpp)(Brip)](n) (M = Co-II (1) and Ni-II (2), bpp = 1,3-bi(4-pyridyl)propane, H(2)Brip = 5-bromoisophthalic acid), have been synthesized through hydrothermal reaction. They were characterized by elemental analysis, IR spectra, thermal analysis, magnetic properties, and X-ray single-crystal diffraction. The two complexes belong to monoclinic system, C2/c space group. The adjacent Co-II or Ni-II ions are bridged by Brip to form an alternate 1D chain. Such 1D chains are further connected by bpp to generate a twofold interpenetrating diamondoid 3D network. Variable-temperature magnetic susceptibility measurements indicate the occurrence of weak ferromagnetic interactions between the Co-II (1) and Ni-II (2) ions, respectively.
引用
收藏
页码：590 / 595
页数：6
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