Synthesis, structure, and properties of a new representative of the family of calix[4]arene-containing [MnII 2MnIII 2]-clusters

被引：11
|
作者：
Aldoshin, S. M. [1 ]
Antipin, I. S. [2 ]
Ovcharenko, V. I. [3 ]
Solov'eva, S. E. [2 ]
Bogomyakov, A. S. [3 ]
Korchagin, D. V. [1 ]
Shilov, G. V. [1 ]
Yur'eva, E. A. [1 ]
Mushenok, F. B. [1 ]
Bozhenko, K. V. [1 ]
Utenyshev, A. N. [1 ]
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
[2] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia
[3] Russian Acad Sci, Int Tomog Ctr Inst, Siberian Branch, Novosibirsk 630090, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 02期
关键词：
polynuclear manganese complexes; molecular magnets; calix[4]arenes; X-ray crystallography; SQUID-magnetometry;
D O I：
10.1007/s11172-013-0074-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new representative of calix[4]arene-containing tetranuclear manganese complexes of the [Mn-II Mn-2(III) (2)] type was obtained. According to the data of magnetoochemical studies, the complex exhibits properties of molecular magnet at the temperature below 5 K. Parameters of the exchange interaction and the activation energy were determined. The influence of the peripheral environment on the magnetic properties of the tetranuclear manganese framework in the structure of the complex was revealed.
引用
收藏
页码：536 / 542
页数：7
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