Surface-Initiated Living Radical Polymerizations Using Iodine, Organotellurium, and Organic Catalysts

被引：2

作者：

Goto, Atsushi ^{[1
]}

Tsujii, Yoshinobu ^{[1
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan

来源：

CONTROLLED RADICAL POLYMERIZATION AT AND FROM SOLID SURFACES | 2016年 / 270卷

关键词：

Iodine; Organic catalyst; Organotellurium; Polymer brush; Surface-initiated living radical polymerization; VINYLIDENE FLUORIDE VDF; METHYL-METHACRYLATE; POLYMER BRUSHES; MEDIATED POLYMERIZATION; NITROGEN CATALYST; KINETICS; MECHANISM; RTCP; STYRENE; CHAINS;

D O I：

10.1007/12_2015_310

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This chapter reviews surface-initiated living radical polymerizations via iodine transfer polymerization (ITP), organotellurium-mediated radical polymerization (TERP), and reversible chain-transfer catalyzed polymerization (RTCP) using organic catalysts. The successful application of these polymerizations made it possible to graft various polymers with well-defined structures onto flat substrates and nanoparticles. Living radical polymerizations, including ITP, TERP, and RTCP, also lead to a striking increase in the graft density. Because of their unique advantages as synthetic tools, ITP, TERP, and RTCP can be used to expand the scope of controlled surface modification.

引用

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页码：107 / 122

页数：16

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