The reactions of 3,6-di-tert-butyl-1,2-benzoquinone and 3,6-di-tert-butylcatechol with tert-butyl hydroperoxide

被引：3
|
作者：
Glushakova, VN [1 ]
Skorodumova, NA [1 ]
Nevodchikov, VI [1 ]
Abakumova, LG [1 ]
Makarenko, NP [1 ]
Cherkasov, VK [1 ]
Druzhkov, NO [1 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603600, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 05期
关键词：
tert-butyl hydroperoxide; 3,6-di-tert-butyt-1,2-benzoquinone; 3,6-di-tert-butylcatechol; alkylperoxy radicals; alkyloxy radicals; semiquinone radicals;
D O I：
10.1007/BF02494640
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of 3,6-di-tert-butyl-1,2-benzoquinone and 3,6-di-tert-butylcatechol with tert-butyl hydroperoxide in aprotic solvents leads to the generation of semiquinone (SQ(.)H), alkylperoxy (ROO.), and alkyloxy radicals. The reaction of SQ(.)H and ROO. produces 2, 5-di-tert-butyl-6-hydroxy-1,4-benzoquinone, 3,6-di-tert-butyl-1-oxacyclohepta-3, 5-diene-2,7-dione, and 2,5-di-tert-butyl-3,6-dihydroxy-1,4-benzoquinone, The radical generated from solvent attacks SQ(.)H at position 4 with C-C bond formation. 4-Benzyl-2,5-di-tert-butyl-6-hydroxycyclohexa-2,5-diene-1-dione produced in this way is transformed into 4-benzyl-3,6-di-tert-butyl-1,2-benzoquinone under the reaction conditions.
引用
收藏
页码：934 / 937
页数：4
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