Facile Cu(I)-Catalyzed Oxidative Coupling of Anilines to Azo Compounds and Hydrazines with Diaziridinone under Mild Conditions

被引：85
|
作者：
Zhu, Yingguang [1 ]
Shi, Yian [1 ]
机构：
[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
来源：
ORGANIC LETTERS | 2013年 / 15卷 / 08期
基金：
美国国家卫生研究院;
关键词：
PRIMARY AROMATIC-AMINES; CATALYZED AEROBIC DEHYDROGENATION; PD(0)-CATALYZED DIAMINATION; CONJUGATED DIENES; ORGANIC-COMPOUNDS; TERMINAL OLEFINS; REGIOSELECTIVE DIAMINATION; O-BENZENEDISULFONIMIDES; ASYMMETRIC DIAMINATION; GOLD NANOPARTICLES;
D O I：
10.1021/ol4005917
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A mild and highly efficient Cu(I)catalyzed oxidative coupling of anilines is described. Various primary and secondary anilines can be efficiently coupled under mild conditions to the corresponding azo compounds and hydrazines in high yields. This method provides a direct and practical access to these compounds and is also amenable to gram scale with no special precautions to exclude air or moisture.
引用
收藏
页码：1942 / 1945
页数：4
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