Synthesis and Characterization of a Novel Phenol-tailed Porphyrin Ligand and Its Iron(III) Complex

被引：5
|
作者：
Ma, Ben [1 ]
Jiang, Jiaxun [1 ]
Hu, Chuanjiang [1 ,2 ,3 ]
机构：
[1] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
[2] Nanjing Univ, State Key Lab, Nanjing 210093, Jiangsu, Peoples R China
[3] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2013年 / 639卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Iron porphyrins; Iron; Model compounds; Phenol; Crystal structure; HYDROGEN-BOND; MODELS; HEME;
D O I：
10.1002/zaac.201200558
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The phenol-tailed porphyrin ligand, H3L was synthesized as a model compound for catalases. H3L and its corresponding iron complex [Fe(L)] were synthesized by using the precursor, 5-(8-ethoxycarbonyl-1-naphthyl)-10, 15, 20-triphenyl porphyrin (ENTPP). They were characterized by 1H NMR spectroscopy, mass spectrometry, X-ray crystallography, and cyclic voltammetry. All the results have confirmed that the phenol group is covalently attached to the porphyrin. In the iron complex, phenolate oxygen is coordinated to iron(III) as the fifth ligand, leading to the five-coordinate high-spin iron(III) species.
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页码：676 / 680
页数：5
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