Recent advances in the selective catalytic reduction of NOx with NH3 on Cu-Chabazite catalysts

被引:295
|
作者
Wang, Jihui [1 ]
Zhao, Huawang [1 ]
Haller, Gary [2 ]
Li, Yongdan [1 ,2 ]
机构
[1] Tianjin Univ, Sch Chem Engn, State Key Lab Chem Engn,Tianjin Key Lab Appl Cata, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
[2] Yale Univ, Dept Chem & Environm Engn, 9 Hillhouse Ave, New Haven, CT 06511 USA
关键词
Selective catalytic reduction of NOx with ammonia; Cu-Chabazite structured zeolite; Hydrothermal stability; Reaction mechanism; Preparation; STATE ION-EXCHANGE; CU-SAPO-34 MONOLITH CATALYST; CU/SSZ-13 NH3-SCR CATALYSTS; ONE-POT SYNTHESIS; CU/SAPO-34; CATALYSTS; LOW-TEMPERATURE; ACTIVE-SITES; HYDROTHERMAL STABILITY; CU-SSZ-13; CATALYST; MOLECULAR-SIEVES;
D O I
10.1016/j.apcatb.2016.09.024
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The development of Cu-chabazite (CHA) catalysts, i.e. Cu-SSZ-13 and Cu-SAPO-34, represents a significant technology breakthrough for the removal of NOx by selective catalytic reduction (SCR) with ammonia. Cu-CHA catalysts show an excellent hydrothermal stability towards high temperature aging and wide active temperature windows for the ammonia SCR reaction. This work summarizes the recent progress in the development of the Cu-CHA catalysts for the NH3-SCR reaction. The state of Cu in the reaction and the preparation methods on the catalytic performance are discussed. The advances in the understanding of the reaction mechanism are reviewed. The hydrothermal stability of the typical Cu-CHA catalysts are compared. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:346 / 354
页数:9
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