Catalyst free C-N bond formation by the reaction of amines with diimides: bulky guanidines

被引：19

作者：

Baishya, Ashim ^{[1
]}

Peddarao, Thota ^{[1
]}

Barman, Milan Kr. ^{[1
]}

Nembenna, Sharanappa ^{[1
]}

机构：

[1] Natl Inst Sci Educ & Res, Sch Chem Sci, Bhubaneswar 751005, Orissa, India

来源：

NEW JOURNAL OF CHEMISTRY | 2015年 / 39卷 / 09期

关键词：

OXIDATION-STATE METALLACYCLES; COORDINATION CHEMISTRY; SUBSTITUTED GUANIDINES; AMIDE COMPLEXES; EFFICIENT ROUTE; GUANYLATION REACTION; TISHCHENKO REACTION; SECONDARY-AMINES; CARBODIIMIDES; DERIVATIVES;

D O I：

10.1039/c5nj01612f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have shown an atom economical and catalyst free addition of cyclic secondary amines to various bulky aryl symmetrical and unsymmetrical carbodiimides to afford N, N'N '' N ''-tetra substituted guanidines in quantitative yields at ambient reaction conditions. Furthermore, it was established that the addition of diamine to bulky aryl symmetrical carbodiimides (2 equiv.) led to the formation of bulky aryl biguanidines.

引用

页码：7503 / 7510

页数：8

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