A Molecular Platform for Multistate Near-Infrared Electrochromism and Flip-Flop, Flip-Flap-Flop, and Ternary Memory

被引：91

作者：

Cui, Bin-Bin ^{[1
]}

Tang, Jian-Hong ^{[1
]}

Yao, Jiannian ^{[1
]}

Zhong, Yu-Wu ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Photochem, Beijing 100190, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 32期

基金：

中国国家自然科学基金;

关键词：

electrochemistry; memory; molecular device; molecular logic; ruthenium; ELECTROPOLYMERIZED FILMS; ELECTRON-TRANSFER; VOLATILE MEMORY; SOLID SUPPORT; LOGIC; COMPLEX; RUTHENIUM; MONOLAYERS; POLYMERS; DEVICES;

D O I：

10.1002/anie.201504584

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A diruthenium complex with a redox-active amine bridge has been designed, synthesized, and studied by single-crystal X-ray analysis and DFT and TDDFT calculations. It shows three well-separated redox processes with exclusive near-infrared (NIR) absorbance at each redox state. The electropolymerized film of a related vinyl-functionalized complex displays multistate NIR electrochromism with low operational potential, good contrast ratio, and long retention time. Flip-flop, flip-flap-flop, and ternary memories have been realized by using the obtained film (ca. 15-20nm thick) with three electrochemical inputs and three NIR optical outputs that each displays three levels of signal intensity.

引用

页码：9192 / 9197

页数：6

共 50 条

[1] Electrically Addressable Multistate Volatile Memory with Flip-Flop and Flip-Flap-Flop Logic Circuits on a Solid Support
de Ruiter, Graham
Motiei, Leila
Choudhury, Joyanta
Oded, Noa
van der Boom, Milko E.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (28) : 4780 - 4783
[2] Flip-flop flap
Reebs, Stephan
NATURAL HISTORY, 2007, 116 (07) : 12 - 12
[3] Flip-flop flap
Steffens, Holger
EDN, 2009, 54 (08)
[4] Flip-flop flap
Steffens, Holger
EDN, 2009, 54 (07) : 65 - 65
[5] TERNARY FLIP-FLOP CIRCUIT
RATH, SS
INTERNATIONAL JOURNAL OF ELECTRONICS, 1975, 38 (01) : 41 - 47
[6] NOVEL TERNARY JKL FLIP-FLOP
ZHUANG, N
WU, H
ELECTRONICS LETTERS, 1990, 26 (15) : 1145 - 1146
[7] The postauricular island flap (flip-flop flap)
Leong, Samuel C.
Karkos, Petros D.
Hampal, Sucha
ENT-EAR NOSE & THROAT JOURNAL, 2009, 88 (12) : 1256 - 1257
[8] CONSTRUCTIONS OF TERNARY FLIP-FLOP CIRCUITS.
Muranaka, Noriaki
Imanishi, Shigeru
Systems, computers, controls, 1984, 15 (03): : 1 - 9
[9] Design of ternary flip-flop and its transformation
Fang, Zhenxian
Tien Tzu Hsueh Pao/Acta Electronica Sinica, 1993, 21 (11): : 95 - 98
[10] A charge-driven molecular flip-flop
Wang, Yu
Zhao, Yanjiao
Huang, Jiping
EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 2013, 61 (03):

← 1 2 3 4 5 →