Synthesis, Crystal Structures and DNA-Binding of Cu(II), Zn(II) Coordination Polymer Constructed from 4-Hydroxyphenylacetic Acid

被引：0

作者：

Wu Xiao-Yong ^{[1
]}

Liu Jian-Feng ^{[1
]}

Zhao Guo-Liang ^{[1
,2
]}

机构：

[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Jinhua 321004, Zhejiang, Peoples R China

[2] Zhejiang Normal Univ, Xingzhi Coll, Jinhua 321004, Zhejiang, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 28卷 / 08期

关键词：

transition metal complex; 4-hydroxyphenylacetic acid; crystal structure; DNA-binding; TRANSITION-METAL-COMPLEXES; BASE; POLYPYRIDYL;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two transition metal complexes [M(HPAA)(phen)(2)]HPAA center dot 7H(2)O(M=Zn, 1; Cu, 2; HPAA(-)=-4-hydroxyphenylacetic acid anion; phen=1,10-phenanthroline) were sythesized and characterized by elemental analysis, IR and TG-DTG. Their crystal structures were determined by single crystal X-ray diffraction method. The crystal structure anlysis reveals two complexes belong to isomorphism, and the asymmetric unit contains one metal ion, two 4-hydroxyphenylacetic acid anions and seven free water molecules, one of acid anions is not coordinated with the metal ion. The metal ion is six-coordinated and involved in a distorted octahedral coordination geometry. In addition, the interaction of complexes with DNA were also studied by ethidium bromide (EB) fluorescence spectroscopy. CCDC: 729804, 1; 729805, 2.

引用

页码：1661 / 1667

页数：7

共 20 条

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