Study for Synthesis and Ionic Conductivity of Polyionomer Lithium Tetrafluoroborate Film for Secondary Lithium Battery Polymeric Electrolytes

被引：1

作者：

Kim, Beom-Ju ^{[1
]}

Kim, Young-Seok ^{[1
]}

Choi, Seong-Ho ^{[1
]}

机构：

[1] Hannam Univ, Dept Chem, Taejon 305811, South Korea

来源：

JOURNAL OF NANOELECTRONICS AND OPTOELECTRONICS | 2015年 / 10卷 / 04期

基金：

新加坡国家研究基金会;

关键词：

Secondary Lithium Battery Polymeric Electrolytes; Vinyl Polyionomer Lithium Tetrafluoroborate Film; Poly(1-[(4-ethenylphenyl)methyl]-3-buthyl-imidazolium lithium tetrafluoroborate) Film; Poly(3-octyl-1-vinylimidazolium lithium tetrafluoroborate Film; lon Conductivity; POLYESTERS;

D O I：

10.1166/jno.2015.1795

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

Novel polyionomer lithium tetrafluoroborates including poly(1-[(4-ethenylphenyl)methyl]-3-buthyl imidazolium lithium tetrafluoroborate) (poly(EMBI/Li+)) and lithium tetrabonate poly(3-octyl-1-vinyl imidazolium lithium tetrafluoroborate) (poly(OVI/Li+)) films were synthesized for use as polymeric electrolytes in secondary lithium battery cells. The successfully synthesized of vinyl monomer with ionic properties and polyioners were confirmed via 1H-NMR, FT-IR, GC-Mass, Scanning Electron Microscopy (SEM), and impedance analysis, respectively. From impedance analysis, the ion conductivity of the poly(OVI/Li+) and poly(EMBI/Li+) films is shown as 2.69x10(-4) S/cm and 5.00x10(-7) S/cm respectively. The prepared poly(OVI/Li+) film is suitable for use as secondary lithium battery polymeric electrolyte.

引用

页码：524 / 529

页数：6

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