New type clathrate of the 3D metal complex host (N-methyl-1,3-diaminopropane)cadmium(II) tetracyanocadmate(II)

被引：3

作者：

Kitazawa, T

机构：

[1] Department of Chemistry, Faculty of Science, Toho University, Miyama, Funabashi

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1996年 / 276卷

关键词：

D O I：

10.1080/10587259608039374

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A new clathrate compound Cd(mon)Cd(CN)(4) . Cl-ClCH2Cl (mtn = N-methyl-1,3-diaminopropane)is prepared and characterized to contain tetrahedral and octahedral Cd atoms in a ratio of 1:1, mtn chelating to the latter. A pair of 1,2-dichloroethane guest molecules are accommodated in a cavity of the host framework. The arrangement of octahedral and tetrahedral Cd atoms is different from that of the previously reported Cd(pn)Cd(CN)(4) . CH2ClCH2Cl (pn = 1,2-diaminopropane) which has the same composition.

引用

页码：167 / 172

页数：6

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