Chemoselective synthesis of (allyloxy)carbene chelate complexes of iron

被引：5

作者：

Schulz, C ^{[1
]}

Tohier, M ^{[1
]}

Sinbandhit, S ^{[1
]}

Guerchais, V ^{[1
]}

机构：

[1] Univ Rennes 1, UMR 6509 CNRS, F-35042 Rennes, France

来源：

INORGANICA CHIMICA ACTA | 1999年 / 291卷 / 1-2期

关键词：

iron complexes; chelate complexes; alkene-carbene complexes;

D O I：

10.1016/S0020-1693(99)00040-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chelate (allyloxy)carbene complexes [Fe(C5H5)(CO){eta(2)-C(OCH2CH = CHPh)C6H4-o-X}][OTf] (4a-b) (a, X = OMe: b, X = Cl) are readily accessible from methoxycarbene complexes 2 and 3 containing a hemilabile or labile ligand. The facile coordination of the alkenyl group, due to the presence of a potential vacant coordination site, allows the selective formation of 4. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：449 / 451

页数：3

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