Chemoselective synthesis of (allyloxy)carbene chelate complexes of iron

被引：5
|
作者：
Schulz, C [1 ]
Tohier, M [1 ]
Sinbandhit, S [1 ]
Guerchais, V [1 ]
机构：
[1] Univ Rennes 1, UMR 6509 CNRS, F-35042 Rennes, France
来源：
INORGANICA CHIMICA ACTA | 1999年 / 291卷 / 1-2期
关键词：
iron complexes; chelate complexes; alkene-carbene complexes;
D O I：
10.1016/S0020-1693(99)00040-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chelate (allyloxy)carbene complexes [Fe(C5H5)(CO){eta(2)-C(OCH2CH = CHPh)C6H4-o-X}][OTf] (4a-b) (a, X = OMe: b, X = Cl) are readily accessible from methoxycarbene complexes 2 and 3 containing a hemilabile or labile ligand. The facile coordination of the alkenyl group, due to the presence of a potential vacant coordination site, allows the selective formation of 4. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：449 / 451
页数：3
相关论文
共 50 条
  • [1] THE CLAISEN REARRANGEMENT OF IRON ALLYLOXY CARBENE COMPLEXES
    BARRETT, AGM
    CARPENTER, NE
    ORGANOMETALLICS, 1987, 6 (10) : 2249 - 2250
  • [2] Ruthenium tris(pyrazolyl)borate complexes.: 14.: Synthesis and characterization of (allyloxy)carbene complexes
    Rüba, E
    Gemel, C
    Slugovc, C
    Mereiter, K
    Schmid, R
    Kirchner, K
    ORGANOMETALLICS, 1999, 18 (11) : 2275 - 2280
  • [3] CHEMOSELECTIVE OXIDATION OF [(ARYLTHIOALKYLPYRROLIDINO)CARBENE]CHROMIUM(O) PENTACARBONYL COMPLEXES - SYNTHESIS OF (ARYLSULFINYL AND ARYLSULFONYLALKYL PYRROLIDINO)CARBENE COMPLEXES
    BALDOLI, C
    DELBUTTERO, P
    LICANDRO, E
    MAIORANA, S
    PAPAGNI, A
    SYNLETT, 1995, (06) : 666 - 668
  • [4] Higher MLCT lifetime of carbene iron(II) complexes by chelate ring expansion
    Reuter, Thomas
    Kruse, Ayla
    Schoch, Roland
    Lochbrunner, Stefan
    Bauer, Matthias
    Heinze, Katja
    CHEMICAL COMMUNICATIONS, 2021, 57 (61) : 7541 - 7544
  • [5] Functionalised and chelate heterocyclic carbene complexes of palladium; synthesis and structural studies
    Tulloch, AAD
    Winston, S
    Danopoulos, AA
    Eastham, G
    Hursthouse, MB
    DALTON TRANSACTIONS, 2003, (04) : 699 - 708
  • [6] SYNTHESIS OF (ALLYLOXY)(ALKYNYL)CARBENE COMPLEXES AND THEIR REACTION WITH OCTACARBONYLDICOBALT - AN UNPRECEDENTED RETRO-FISCHER REACTION
    CHRISTOFFERS, J
    DOTZ, KH
    ORGANOMETALLICS, 1994, 13 (11) : 4189 - 4193
  • [7] SYNTHESIS AND STRUCTURE OF CHELATE OLEFINCARBAMYLATE COMPLEXES OF IRON CARBONYLS
    NESMEYANOV, AN
    SALNIKOVA, TN
    STRUCHKOV, YUT
    ANDRIANOV, VG
    POGREBNYAK, AA
    RYBIN, LV
    RYBINSKAYA, MI
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 117 (01) : C16 - C20
  • [8] IRON CARBENE COMPLEXES AS REAGENTS FOR ORGANIC-SYNTHESIS
    HELQUIST, P
    KNORS, C
    BRINKMAN, K
    KUO, GH
    LYON, C
    ZHAO, SK
    SEUTET, P
    MATTSON, M
    IYER, RS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 75 - ORGN
  • [9] Hemilabile properties of chelate iron complexes: Synthesis and structure of oxametallacycles
    Poignant, G
    Sinbandhit, S
    Toupet, L
    Guerchais, V
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 1998, (10) : 1387 - 1389
  • [10] Synthesis and characterization of high-spin iron carbene complexes
    Wrobel, Alexandra
    Betley, Theodore
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
12345