Synthesis of ?-MnS/nanoporous carbon/reduced graphene oxide composites for high-performance supercapacitor

被引:8
|
作者
Olatoye, Abiola Ganiyat [1 ,2 ]
Zhang, Jie [1 ,2 ]
Wang, Qianyu [1 ,2 ]
Cao, Erping [1 ,2 ]
Li, Wenli [1 ,2 ]
Fagbohun, Emmanuel Oluwaseyi [1 ,2 ]
Cui, Yanbin [1 ,2 ]
机构
[1] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
关键词
Metal-organic framework; Nanoporous carbon; Reduced graphene oxide; -MnS; Supercapacitor; METAL-ORGANIC FRAMEWORKS; ELECTRODE MATERIALS; ENERGY-STORAGE; CARBON; ZIF-8; NITROGEN; NANOPARTICLES; NANOCOMPOSITE; FABRICATION; CAPACITY;
D O I
10.1016/j.crcon.2022.06.002
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In the present work, nanoporous carbon (NPC) was prepared from a metal???organic framework (zeolite imidazolate framework 8, ZIF-8). Different concentrations of graphene oxide (GO) were used to make NPC/reduced graphene oxide (NPC/rGO-x, x = 0.5, 1.0, 1.5, and 2.0) composites, and then ??-MnS/NPC/rGO-1 composite was synthesized via a simple hydrothermal technique. The electrochemical characteristics of porous carbon composites (NPC/rGO-x) and ??-MnS/NPC/rGO-1 electrodes were investigated by galvanostatic charge and discharge, cyclic voltammetry, and electrochemical impedance spectroscopy. NPC/rGO-1 showed the highest specific capacitance of 207 F/g at 0.5 A/g. Also, the ??-MnS/NPC/rGO-1 electrode demonstrates exceptional electrochemical performance with a high specific capacitance of 300 F/g at 0.5 A/g and impressive cyclic stability of 70% capacitance retention after 10,000 cycles at 1 A/g. As a result, this study demonstrates that ??-MnS/NPC/ rGO-1 electrode can be considered a promising candidate for high-performance supercapacitors.
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页码:222 / 230
页数:9
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