Long-lived charge separation in a donor-acceptor dyad adsorbed in mesoporous MCM-41

被引:17
|
作者
Kuchi, V [1 ]
Oliver, AM [1 ]
Paddon-Row, MN [1 ]
Howe, RF [1 ]
机构
[1] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia
关键词
D O I
10.1039/a902187f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Irradiation of a rigid donor-{6-bond-bridge}-acceptor dyad [donor = dimethoxynaphthalene (DMN); acceptor = dicyanovinyl (DCV)] occluded within the pores of mesoporous MCM-41 containing aluminium leads to the formation of the DCV radical anion of the dyad with a lifetime of days.
引用
收藏
页码:1149 / 1150
页数:2
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