Reaction of alkylsulfanylchloroacetylenes with 1,1-dimethylhydrazine

被引：0
|
作者：
Voronkov, MG [1 ]
Lebedeva, IP
Petrova, AA
Rakhlin, VI
D'yachkova, SG
机构：
[1] Russian Acad Sci, Siberian Div, Favorskii Irkutsk Inst Chem, Irkutsk 664033, Russia
[2] Irkutsk State Tech Univ, Irkutsk, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 41卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1007/s11178-005-0366-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Alkylsulfanylchloroacetylenes react with 1,1-dimethylhydrazine in diethyl ether at 20-22 degrees C to give, depending on the reactant ratio, 3,6-bis(alkylsulfanylmethyl)-1,1,4,.4-tetramethyl-1,4-dihydro-1,2,4,5-tetrazine-1,4-diium dichlorides (yield 67-80%) or 1-[2-(alkylsulfanyl)-1-(2,2-dimetbylhydrazono)ethyl]-1,1-dimethylhydrazinium chlorides. The latter readily undergo dequaternization to the corresponding 2-alkylsultanyl-N-1,N-2,N-4-trimethylethanohydrazide hydrazones (yield up to 53%).
引用
收藏
页码：1458 / 1462
页数：5
相关论文
共 50 条
  • [31] MOLECULAR-STRUCTURE OF 1,1-DIMETHYLHYDRAZINE
    LITVINOV, OA
    ERMOLAEVA, LV
    ZVEREV, VV
    NAUMOV, VA
    JOURNAL OF STRUCTURAL CHEMISTRY, 1989, 30 (02) : 224 - 228
  • [32] Alkylation of 1,1-dimethylhydrazine with functional halo derivatives: Synthetic potential of the reaction
    Kochkina, EN
    Belobrzhetskaya, MK
    Lokteva, NV
    Malin, AS
    Laskin, BM
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 1999, 72 (12) : 2082 - 2087
  • [33] Products of reaction of 1,1-dimethylhydrazine with propargyl bromide and 1,3-dibromopropyne
    Elokhina, VN
    Larina, LI
    Nakhmanovich, AS
    Lopyrev, VA
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2000, 70 (11) : 1752 - 1754
  • [34] REACTION OF CHLORAMINE WITH 1,1-DIMETHYLHYDRAZINE - FORMATION OF TETRAMETHYL-2-TETRAZENE
    SISLER, HH
    KREN, RM
    UTVARY, K
    INORGANIC CHEMISTRY, 1969, 8 (09) : 2007 - &
  • [35] REACTION-KINETICS AND MECHANISM OF HETEROGENIC OXIDATION OF 1,1-DIMETHYLHYDRAZINE BY OZONE
    EMELYANOVA, GI
    LYSENKO, TF
    ATYAKSHEVA, LF
    STRAKHOV, BV
    ZHURNAL FIZICHESKOI KHIMII, 1977, 51 (01): : 85 - 88
  • [36] GAS-PHASE REACTION OF 1,1-DIMETHYLHYDRAZINE WITH NITROGEN-DIOXIDE
    TUAZON, EC
    CARTER, WPL
    BROWN, RV
    WINER, AM
    PITTS, JN
    JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (09): : 1600 - 1605
  • [37] SURFACE-CHEMISTRY OF 1,1-DIMETHYLHYDRAZINE ON PLATINUM
    SCHWANER, AL
    KOVAR, M
    ALBERAS, DJ
    WHITE, JM
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1995, 13 (03): : 1368 - 1372
  • [38] Entropy effects in the fragmentation of 1,1-dimethylhydrazine ions
    Boulanger, Anne-Marie
    Rennie, Emma E.
    Holland, David M. P.
    Shaw, David A.
    Mayer, Paul M.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (25): : 5388 - 5398
  • [39] PHOTOREACTIONS OF AROMATIC-COMPOUNDS WITH 1,1-DIMETHYLHYDRAZINE
    GILBERT, A
    KRESTONOSICH, S
    RIVAS, C
    ACTA CIENTIFICA VENEZOLANA, 1988, 39 (01): : 99 - 100
  • [40] Synthesis and phosphorylation of enamides based on 1,1-dimethylhydrazine
    Rozinov, VG
    Kolbina, VE
    Rozinova, LG
    Lopyrev, VA
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 1999, 69 (05) : 833 - 834
12345