Structure and Magnetic Properties of an Original {CuIIMnIIWV} Heterotrimetallic Coordination Polymer

被引：1
|
作者：
Alexandru, Maria-Gabriela [1 ]
Visinescu, Diana [2 ]
Madalan, Augustin M. [3 ]
Clerac, Rodolphe [4 ]
Andruh, Marius [3 ]
机构：
[1] Univ Politehn Bucuresti, Fac Appl Chem & Mat Sci, Dept Inorgan Chem Phys Chem & Electrochem, 1-7 Gh Polizu St, Bucharest 01106, Romania
[2] Romanian Acad, Ilie Murgulescu Inst Phys Chem, Coordinat & Supramol Chem Lab, Splaiul Independentei 202, Bucharest 060021, Romania
[3] Univ Bucharest, Fac Chem, Inorgan Chem Lab, Str Dumbrava Rosie 23, Bucharest 020464, Romania
[4] Univ Bordeaux, CNRS, Ctr Rech Paul Pascal, UMR 5031, F-33600 Pessac, France
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2020年 / 2020卷 / 32期
关键词：
Heterotrimetallic chains; Cyanides; Metalloligands; Structure elucidation; Magnetic properties; CRYSTAL-STRUCTURES; LIGANDS;
D O I：
10.1002/ejic.202000469
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A monodimensional heterotrimetallic coordination polymer of formula(1)(infinity)[{(CuMnL2)-Mn-II-L-II}(3){(mu-NC)(3)W-V(CN)(5)}(2)]center dot H2O (1) has been assembled from pre-designed [(CuMnL2)-Mn-II-L-II](2+)cationic modules and homoleptic [W-V(CN)(8)](3-)metalloligands (H(2)L(2)is the compartmental Schiff-base resulting from the stepwise condensation of 2,6-diformyl-p-cresol with ethylenediamine and diethylenetriamine). The magnetic properties of1have been investigated revealing a three-dimensional ordered antiferromagnetic ground state below 4 K resulting from different antiferromagnetic interactions between all the spin carriers (S= 1/2 Cu-II,S= 5/2 Mn-II, andS= 1/2 W(V)centers).
引用
收藏
页码：3111 / 3114
页数：4
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