Aniline chlorination by in situ formed Ag-Cl complexes under simulated solar light irradiation

被引：4
|
作者：
Hu, Xuefeng [1 ,2 ]
Wang, Xiaowen [1 ,2 ]
Dong, Liuliu [1 ,4 ]
Chang, Fei [3 ]
Luo, Yongming [1 ,2 ]
机构：
[1] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Univ Shanghai Sci & Technol, Sch Environm & Architecture, Shanghai 200093, Peoples R China
[4] Yantai Univ, Environm & Mat Engn, Yantai 264005, Shandong, Peoples R China
来源：
WATER SCIENCE AND TECHNOLOGY | 2015年 / 71卷 / 11期
基金：
中国国家自然科学基金;
关键词：
aniline; Ag-Cl complexes; Cl/Ag ratio; photochlorination; RATE CONSTANTS; SALINE WATER; PHOTOCHLORINATION; ACETONITRILE; DEGRADATION; IONS;
D O I：
10.2166/wst.2015.149
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Ag speciation in a chloride medium was dependent upon the Cl/Ag ratio after releasing into surface water. In this study, the photoreaction of in situ formed Ag-Cl species and their effects on aniline photochlorination were systematically investigated. Our results suggested that formation of chloroaniline was strongly relevant to the Cl/Ag ratio and could be interpreted using the thermodynamically expected speciation of Ag in the presence of Cl-. AgCl was the main species responsible for the photochlorination of aniline. Both photoinduced hole and center dot OH drove the oxidation of Cl- to radical center dot Cl, which promoted the chlorination of aniline. Ag-0 formation was observed from the surface plasmon resonance absorption during AgCl photoreaction. This study revealed that Ag+ released into Cl--containing water may result in the formation of chlorinated intermediates of organic compounds under solar light irradiation.
引用
收藏
页码：1679 / 1685
页数：7
相关论文
共 50 条
  • [31] Hydrogenated Cagelike Titania Hollow Spherical Photocatalysts for Hydrogen Evolution under Simulated Solar Light Irradiation
    Wang, Yating
    Cai, Jinmeng
    Wu, Moqing
    Zhang, Hao
    Meng, Ming
    Tian, Ye
    Ding, Tong
    Gong, Jinlong
    Jiang, Zheng
    Li, Xingang
    ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (35) : 23006 - 23014
  • [32] In-situ growth of Ag3PO4 on calcined Zn-Al layered double hydroxides for enhanced photocatalytic degradation of tetracycline under simulated solar light irradiation and toxicity assessment
    Chen, Chaorong
    Zeng, Hongyan
    Yi, Moyu
    Xiao, Gaofei
    Xu, Sheng
    Shen, Shigen
    Feng, Bo
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 252 : 47 - 54
  • [33] Preparation and characterisation of Ag modified rutile titanium dioxide and its photocatalytic activity under simulated solar light
    Zhu, Xiaodong
    Han, Shihu
    Zhu, Dongzhi
    Chen, Shanhua
    Feng, Wei
    Kong, Qingquan
    MICRO & NANO LETTERS, 2019, 14 (07) : 757 - 760
  • [34] Degradation and Mineralization of Bisphenol A by Mesoporous Bi2WO6 under Simulated Solar Light Irradiation
    Wang, Chunying
    Zhang, Hao
    Li, Fang
    Zhu, Lingyan
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2010, 44 (17) : 6843 - 6848
  • [35] Silicon nanowire/TiO2 heterojunction arrays for effective photoelectrocatalysis under simulated solar light irradiation
    Yu, Hongtao
    Chen, Shuo
    Quan, Xie
    Zhao, Huimin
    Zhang, Yaobin
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 90 (1-2) : 242 - 248
  • [36] Porous Si/TiO2 nanowire photoanode for photoelectric catalysis under simulated solar light irradiation
    Chen, Zhangxiaoxiong
    Yang, Jikai
    Yang, Xiaotian
    Zhao, Yiming
    Kang, Jiaqi
    Yang, Fuyu
    Zhang, Yufei
    Cheng, Ming
    Wang, Guozheng
    Duanmu, Qingduo
    APPLIED ORGANOMETALLIC CHEMISTRY, 2018, 32 (06)
  • [37] Catalytic role of Cu(II) in the reduction of Cr(VI) by citric acid under an irradiation of simulated solar light
    Li, Ying
    Chen, Cheng
    Zhang, Jing
    Lan, Yeqing
    CHEMOSPHERE, 2015, 127 : 87 - 92
  • [38] Photodegradation of carbamazepine with BiOCl/Fe3O4 catalyst under simulated solar light irradiation
    Chen, Hongche
    Wang, Xiaoning
    Bi, Wenlong
    Wu, Yanlin
    Dong, Wenbo
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 502 : 89 - 99
  • [39] Study on the photogenerated charge transfer and photoelectrocatalytic performance of Ag/ZnO nanorod arrays under the irradiation of simulated sun light
    Mu, Zhao
    Yan, Weiping
    Zhao, Rusong
    Lin, Yanhong
    MATERIALS RESEARCH EXPRESS, 2015, 2 (06):
  • [40] Antibacterial activities of Nd doped and Ag coated TiO2 nanoparticles under solar light irradiation
    Bokare, Anuja
    Sanap, Avinash
    Pai, Mrinal
    Sabharwal, Sushma
    Athawale, Anjali A.
    COLLOIDS AND SURFACES B-BIOINTERFACES, 2013, 102 : 273 - 280
12345