Bulk and Surface Properties of ZnTe-ZnS System Semiconductors

被引：5
|
作者：
Kirovskaya, I. A. [1 ]
Mironova, E. V. [1 ]
Kosarev, B. A. [1 ]
Nor, P. E. [1 ]
Bukashkina, T. L. [1 ]
机构：
[1] Omsk State Tech Univ, Omsk 644050, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2016年 / 90卷 / 10期
关键词：
diamond-like semiconductors; solid solutions; elemental composition; crystal chemical; structural; acid-base properties; active sites; laws;
D O I：
10.1134/S0036024416100174
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Physicochemical studies of a new ZnTe-ZnS semiconductor system are conducted. It is found that at certain ratios of binary components, substitutional solid solutions with a cubic sphalerite structure are formed in this system. Interrelated laws governing changes in the bulk ( crystal chemical, structural) and surface ( acid-base) properties with varying system composition are identified. It is assumed they can be attributed to the nature of the active ( acid-base) sites. The presented data, observed patterns, and an interpretation of them are used not only to confirm earlier proposed mechanisms of atomic-molecular interaction on diamond-like semiconductors, but to search for promising materials for use in highly sensitive selective sensors for environmental and medical purposes as well.
引用
收藏
页码：2029 / 2034
页数：6
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