Synthesis, Structure, and Photoluminescent Properties of a New 3D Metal-Organic Framework with Unusual AgI Chains

被引：2
|
作者：
Wang, Ji-Jiang [1 ]
Cao, Pei-Xiang [1 ]
Zhang, Mei-Li [1 ]
Gao, Lou-Jun [1 ]
Hou, Xiang-Yang [1 ]
机构：
[1] Yanan Univ, Sch Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2012年 / 638卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Metal-organic framework; Silver; Biphenyl-2; 2'; 4; 4'-tetracarboxylic acid; Ag center dot center dot center dot Ag interactions; COORDINATION; COMPLEXES; NETWORKS; DESIGN;
D O I：
10.1002/zaac.201200140
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 3D metal-organic framework {[Ag4(btc)(bix)2]center dot H2O}n (1) [H4btc = biphenyl-2, 2',4, 4'-tetracarboxylic acid, bix = 1, 4-bis(imidazol-1-ylmethyl)benzene] was synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, infrared (IR) spectroscopy, thermal gravimetric analysis (TGA), and luminescence studies. The most remarkable structural feature of 1 is that the 1D chain and 2D network interpenetrated structures are further linked by parallel aligned 1D AgI chains to generate 3D metal-organic framework.
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页码：1531 / 1534
页数：4
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