Synthesis, Structure, and Photoluminescent Properties of a New 3D Metal-Organic Framework with Unusual AgI Chains

被引：2

作者：

Wang, Ji-Jiang ^{[1
]}

Cao, Pei-Xiang ^{[1
]}

Zhang, Mei-Li ^{[1
]}

Gao, Lou-Jun ^{[1
]}

Hou, Xiang-Yang ^{[1
]}

机构：

[1] Yanan Univ, Sch Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2012年 / 638卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Metal-organic framework; Silver; Biphenyl-2; 2'; 4; 4'-tetracarboxylic acid; Ag center dot center dot center dot Ag interactions; COORDINATION; COMPLEXES; NETWORKS; DESIGN;

D O I：

10.1002/zaac.201200140

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D metal-organic framework {[Ag4(btc)(bix)2]center dot H2O}n (1) [H4btc = biphenyl-2, 2',4, 4'-tetracarboxylic acid, bix = 1, 4-bis(imidazol-1-ylmethyl)benzene] was synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, infrared (IR) spectroscopy, thermal gravimetric analysis (TGA), and luminescence studies. The most remarkable structural feature of 1 is that the 1D chain and 2D network interpenetrated structures are further linked by parallel aligned 1D AgI chains to generate 3D metal-organic framework.

引用

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页码：1531 / 1534

页数：4

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