Recent Progress of N-Heterocyclic Carbene Complexes Synthesized by Poly-imidazolium Salts

被引：2
|
作者：
Lin, Caixia [1 ]
Guo, Lin [2 ,3 ]
Li, Qingshan [2 ,3 ]
Zhang, Zhengzhi [2 ,3 ]
Yuan, Yaofeng [1 ,2 ,3 ]
Xu, Fengbo [2 ,3 ]
机构：
[1] Fuzhou Univ, Dept Chem, Fuzhou 350108, Peoples R China
[2] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
[3] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 34卷 / 02期
基金：
中国国家自然科学基金;
关键词：
N-heterocyclic carbene; poly-imidazolium salts; metal complexes; supramolecular; structure; DEPENDENT COORDINATION MODES; STRUCTURAL-CHARACTERIZATION; PALLADIUM COMPLEX; DINUCLEAR GOLD(I); SILVER(I) COMPLEXES; COPPER(I) COMPLEX; LINKED CYCLOPHANE; CRYSTAL-STRUCTURE; FUNCTIONALIZED N; METAL-COMPLEXES;
D O I：
10.6023/cjoc201307055
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Owing to the excellent chemical stability and catalytic activity, N-heterocyclic carbene (NBC) complexes have always been the hotspot in the field of organic chemistry. Imidazolium salts are the precursors of NHCs, and their easy preparation and structure diversity properties make them useful for the generation of NHC complexes with topology structures. In this paper, the recent progress of synthesis, structure and physicochemical properties of NHC complexes with cylindrical, cage-like, macrocyclic, square and rectangular molecular structures which are synthesized by poly-imidazolium salts is summarized and reviewed.
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收藏
页码：239 / 266
页数：28
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