Chirality Transfer and Memory of Chirality in Gold-Catalyzed Reactions

被引：90

作者：

Patil, Nitin T. ^{[1
]}

机构：

[1] CSIR Indian Inst Chem Technol, CPC Div, Hyderabad 500607, Andhra Pradesh, India

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2012年 / 7卷 / 10期

关键词：

chirality transfer; cyclization; gold; homogeneous catalysis; reaction mechanisms; ASYMMETRIC ALDOL REACTION; GOLD(I)-CATALYZED INTERMOLECULAR HYDROALKOXYLATION; INTRAMOLECULAR CARBOALKOXYLATION; ENANTIOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; EFFICIENT SYNTHESIS; PLATINUM CATALYSIS; ALPHA-AMINOALLENES; ALLYLIC ALCOHOLS; ALLENES;

D O I：

10.1002/asia.201200194

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Over the last few years, gold-catalyzed reactions that involved chirality transfer and memory of chirality (MOC) have emerged as a powerful tool in enantioselective synthesis. This technique has allowed for the single-step synthesis of enantioenriched compounds from readily available starting materials. This Focus Review discusses this emerging field with an emphasis on mechanistic aspects and their applications in synthetic organic chemistry.

引用

页码：2186 / 2194

页数：9

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