Negatively Charged N-Heterocyclic Carbene-Stabilized Pd and Au Nanoparticles and Efficient Catalysis in Water

被引：150

作者：

Ferry, Angelique ^{[1
]}

Schaepe, Kira ^{[1
]}

Tegeder, Patricia ^{[1
]}

Richter, Christian ^{[1
]}

Chepiga, Kathryn M. ^{[1
]}

Ravoo, Bart Jan ^{[1
]}

Glorius, Frank ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

ACS CATALYSIS | 2015年 / 5卷 / 09期

关键词：

metallic nanoparticles; N-heterocyclic carbene; ligand exchange; catalysis; anionic nanoparticles; TRANSITION-METAL NANOPARTICLES; IONIC LIQUIDS; PALLADIUM NANOPARTICLES; RUTHENIUM NANOPARTICLES; GOLD NANOPARTICLES; HECK REACTION; HYDROGENATION; NANOCLUSTERS; NANOCRYSTALS; PRECURSORS;

D O I：

10.1021/acscatal.5b01160

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Herein we describe the synthesis of negatively charged N-heterocyclic carbene (NHC)-functionalized palladium and gold nanoparticles (NPs), which are stable in water for over 3 months. The formation of these NHC NPs proceeds via an efficient ligand exchange procedure. This method was successfully applied to different negatively charged NHCs bearing sulfonate and carboxylate groups. The obtained PdNPs were investigated as catalysts in hydrogenation reactions and showed high catalytic activity (TON up to 2500 and TOF up to 2000 h(-1)).

引用

页码：5414 / 5420

页数：7

共 50 条

[41] Manganese(iii) complexes stabilized with N-heterocyclic carbene ligands for alcohol oxidation catalysis
Rigoni, Giacomo
Nylund, Pamela V. S.
Albrecht, Martin
[J]. DALTON TRANSACTIONS, 2023, 52 (23) : 7992 - 8002
[42] N-Heterocyclic Carbene-Modified Au-Pd Alloy Nanoparticles and Their Application as Biomimetic and Heterogeneous Catalysts
Tegeder, Patricia
Freitag, Matthias
Chepiga, Kathryn M.
Muratsugu, Satoshi
Moeller, Nadja
Lamping, Sebastian
Tada, Mizuki
Glorius, Frank
Ravoo, Bart Jan
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (70) : 18682 - 18688
[43] Guest uptake and heterogeneous catalysis of a porous Pd(II) N-heterocyclic carbene polymer
Lin, Minjuan
Wang, Sujuan
Zhang, Jianyong
Luo, Weijun
Liu, Haoliang
Wang, Wei
Su, Cheng-Yong
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 394 : 33 - 39
[44] N-heterocyclic carbene-stabilized Cu9 clusters with combined thermally activated delayed fluorescence and phosphorescence
Zhang, Lin-Mei
Xie, Mo
Wei, Hui-Zhi
Yuan, Shang-Fu
Li, Dong-Sheng
Wu, Tao
[J]. INORGANIC CHEMISTRY FRONTIERS, 2024, 11 (08) : 2498 - 2507
[45] Perylene diimide-tagged N-heterocyclic carbene-stabilized gold nanoparticles: How much ligand desorbs from surface in presence of thiols?
Belanger-Bouliga, Marilyne
Mahious, Raja
Pitroipa, Poulomsongo Iman
Nazemi, Ali
[J]. DALTON TRANSACTIONS, 2021, 50 (16) : 5598 - 5606
[46] Toward N-heterocyclic carbene stabilized zinc sulfides
Roy, Matthew M. D.
Baird, Samuel R.
Ferguson, Michael J.
Rivard, Eric
[J]. MENDELEEV COMMUNICATIONS, 2021, 31 (02) : 173 - 175
[47] A Borenium Cation Stabilized by an N-Heterocyclic Carbene Ligand
Matsumoto, Takeshi
Gabbaie, Francois P.
[J]. ORGANOMETALLICS, 2009, 28 (15) : 4252 - 4253
[48] Dicationic ditelluride salts stabilized by N-heterocyclic carbene
Nakata, Norio
Kawauchi, Fumihiko
Takahashi, Shintaro
Ishii, Akihiko
[J]. NEW JOURNAL OF CHEMISTRY, 2019, 43 (27) : 10894 - 10898
[49] Zinc Bis(triphenylsilyl) Stabilized by N-Heterocyclic Carbene
Lemmerz, Lara E.
Spaniol, Thomas P.
Okuda, Jun
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2016, 642 (22): : 1269 - 1274
[50] Kinetic Resolutions Enabled by N-Heterocyclic Carbene Catalysis
Yang, Shuang
Fang, Xinqiang
[J]. CURRENT ORGANIC SYNTHESIS, 2017, 14 (05) : 654 - 664

← 1 2 3 4 5 →